Active packaging and food shelf life
Active packaging deliberately interacts with the food or the air around it, for example by soaking up oxygen or releasing an antimicrobial, so the food keeps longer. Ordinary packaging is designed to do the opposite and stay as inert as possible.
What active packaging is
Classic food-contact rules are built on one idea: the packaging should not change the food. Active packaging breaks that rule on purpose, under controlled conditions. EU law defines active materials as materials intended to extend shelf life or to maintain or improve the condition of packaged food, by releasing substances into the food or its surroundings or by absorbing substances from them.
It is often mentioned together with intelligent packaging, but the two are different. Intelligent packaging monitors and tells you something, such as a time-temperature indicator that changes colour if a chilled product warmed up. Active packaging does something to the food's environment.
The principal is simple even if the chemistry isn't: most spoilage is driven by oxygen, moisture, microbes, or ethylene from ripening fruit. Remove the driver, or slow it down, and the food lasts longer.
The main types
Oxygen scavengers
Oxygen makes fats go rancid, changes the colour of meat and lets moulds and many bacteria grow. Modified atmosphere packing flushes most of it out, but some always stays or leaks back in. Oxygen scavengers mop up what's left. The most familiar form is the small iron-powder sachet in a bag of jerky or dried fruit. Newer systems build the scavenger into the packaging layer itself, so there's no separate sachet to throw away or swallow by mistake.
Antimicrobial packaging
Antimicrobial layers release, or carry on their surface, substances that slow the growth of bacteria and moulds on the food. Research has used silver and zinc compounds, but a lot of recent work, including the YPACK project's, focused on natural agents: essential oils such as oregano, eugenol (the main aroma compound in clove oil), and plant extracts. These are attractive because consumers and regulators are more comfortable with them, though their strong taste and smell limit how much can be used.
Moisture absorbers and regulators
The absorbent pad under fresh meat or fish is a type of active packaging. It soaks up drip, which would otherwise look unappetising and feed bacteria. Other systems regulate humidity inside packs of fresh produce, so it doesn't dry out or go slimy.
Ethylene absorbers
Many fruits release ethylene as they ripen, and the gas speeds up ripening in everything nearby. Ethylene absorbers in fruit packs, often based on minerals or potassium permanganate in sachets, slow this chain reaction down.
Emitters
The reverse approach releases something useful, such as carbon dioxide to slow microbial growth, or antioxidants to protect fats.
Active and bio-based together
For bioplastics, active functions solve a real problem. Many bio-based materials have weaker barriers than the conventional multilayers they want to replace. An active layer can make up part of the difference by catching the oxygen that gets through, or by holding back microbial growth.
This was the central idea of YPACK, an EU-funded research project that ran from 2017 to 2021. One of its two prototypes was a multilayer thermoformed tray based on PHA, a bacterially produced bioplastic, with an active inner layer. The project's published research tested, among other things:
- PHBV films carrying oregano essential oil held in cyclodextrin, a ring-shaped sugar molecule that releases the oil slowly;
- PHBV layers with eugenol encapsulated in mesoporous silica particles, for longer-lasting antimicrobial effect;
- PHB films containing palladium nanoparticles that scavenge oxygen;
- multilayer films combining an antimicrobial heat-sealing layer of PHBV with high-barrier cellulose nanocrystals.
Our publications page lists these papers with links. More about the material itself is in the PHA guide.
EU rules for active materials
Because active packaging is designed to interact with food, it gets its own regulation on top of the general rules.
Regulation (EC) No 1935/2004 is the framework for all food contact materials. It says materials must not release substances into food in amounts that could endanger health or change the food unacceptably. It explicitly allows active materials, under conditions.
Regulation (EC) No 450/2009 sets the specific rules for active and intelligent materials. In short: the components that make a pack active need to be on an EU list of authorised substances, after a safety evaluation by EFSA, the European Food Safety Authority. Substances released into the food must also comply with food law, for example the rules on food additives, and the pack must be labelled so the consumer can identify parts that are not to be eaten.
That last point is why oxygen-absorber sachets carry "do not eat" warnings.
For plastic packaging, the plastics regulation, (EU) No 10/2011, applies as well, with its limits on what can migrate into food.
Is it worth it?
Active packaging adds cost and complexity, and it only pays off when the shelf-life gain matters. For fresh meat, fish and cut produce, where a day or two can be the difference between sold and binned, it can. For a dry biscuit, almost never.
The environmental case works the same way. A slightly heavier, more complex pack that prevents food waste can be the greener choice, because producing the food usually has a much bigger footprint than the packaging around it. But that has to be shown case by case, not assumed.
Frequently asked questions
What is active packaging?
What is the difference between active and intelligent packaging?
Is active packaging regulated in the EU?
Sources
- Regulation (EC) No 1935/2004 on materials and articles intended to come into contact with food. Official Journal of the EU, 2004.
- Regulation (EC) No 450/2009 on active and intelligent materials and articles. Official Journal of the EU, 2009.
- Active and intelligent materials. EFSA.
- Development of electrospun active films of PHBV by the incorporation of cyclodextrin inclusion complexes containing oregano essential oil. Figueroa-Lopez K.J. et al., Food Hydrocolloids, 2020.
- Electrospun Antimicrobial Films of PHBV Containing Eugenol Essential Oil Encapsulated in Mesoporous Silica Nanoparticles. Melendez-Rodriguez B. et al., Nanomaterials, 2019.
- Electrospun Oxygen Scavenging Films of Poly(3-hydroxybutyrate) Containing Palladium Nanoparticles for Active Packaging Applications. Cherpinski A. et al., Nanomaterials, 2018.
- YPACK project record (grant agreement 773872). CORDIS, European Commission.